Characterization of Synthesized NiCo2O4 with Trisodium Citrate for Supercapacitor Material: A Preliminary Study
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Keywords:
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NiCo2O4, rGO, Trisodium Citrate, Supercapacitor, Pseudo-capacitor
Abstract
Supercapacitors can be called electrostatic double-layer capacitors (EDLCs) or pseudo-capacitors based on their energy storage mechanism. Pseudo-capacitors with metal oxide electrodes that transmit electric charge offer great application power but low stability. This study aims to characterize trisodium citrate (TSC) modified NiCo2O4/rGO electrodes as a preliminary study for the NiCo2O4 nanoparticle pseudo-capacitor. The materials were characterized using SEM (Scanning Electron Microscopy), XRD (X-Ray Diffractometer), FT-Raman (Fourier Transform Raman Spectroscopy), and FTIR (Fourier Transform Infrared Spectroscopy). All of these analyses confirmed that NiCo2O4 was manufactured successfully using TSC. At XRD, the angles of 2????, namely 45.04 and 53.34°, matched the plane of the cubic phase nanorod crystals of NiCo2O4 with values of 400 and 511, respectively. In the Raman examination, the presence of rGO, which increased the crystallinity of NiCo2O4 nanoparticles, was confirmed. FTIR analysis indicated that the 1550-1600 cm−1 corresponds to a C=C functional group in an aromatic ring or a C=O ????-???? structure, and the wavenumber of 2300 cm−1 corresponds to the OH group in TSC, an alkanoate derivative. SEM analysis determined that NiCo2O4 nanoparticles with 1 mmol TSC are the ideal material for supercapacitor electrodes, as the structure is the most uniform, soft, and tidy. Further analysis is needed to confirm the stability of the modified material.
References
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Aksu, Z., C. H. Şahin, and M. Alanyalıoğlu (2022). Fabrication of Janus GO/rGO Humidity Actuator by One-step Electrochemical Reduction Route. Sensors and Actuators B: Chemical, 354; 131198
Aman, S., M. Z. Ansari, M. Abdullah, A. G. Abid, I. Bashir, M. U. Nisa, S. Manzoor, A. M. Shawky, S. Znaidia, and H. M. T. Farid (2022). Facile Synthesis of CoCo2O4/rGO Spinel Nanoarray as a Robust Electrode for Energy Storage Devices. Inorganic Chemistry Communications, 146; 110136
Bhardwaj, R. and R. Jha (2020). Trisodium Citrate Assisted Morphology Controlled Synthesis of Nickel Sulphide Nanoparticles with Enhanced Cyclic Stability as Carbonaceous Free Electrode Material. Materials Chemistry and Physics, 255; 123581
Bhat, M. Y., S. Hashmi, M. Khan, D. Choi, and A. Qurashi (2023). Frontiers and Recent Developments on Supercapacitor’s Materials, Design, and Applications: Transport and Power System Applications. Journal of Energy Storage, 58; 106104
Chai, L., Y. Wang, Z. Jia, Z. Liu, S. Zhou, Q. He, H. Du, and G. Wu (2022). Tunable Defects and Interfaces of Hierarchical Dandelion-like NiCo2O4 via Ostwald Ripening Process for high efficiency Electromagnetic Wave Absorption. Chemical Engineering Journal, 429; 132547
Dong, W., L. An, X. Wang, B. Li, B. Chen, W. Tang, C. Li, and G. Wang (2011). Controlled Synthesis and Morphology Evolution of Nickel Sulfide Micro/nanostructure. Journal of Alloys and Compounds, 509(5); 2170–2175
Du, F., X. Zuo, Q. Yang, B. Yang, G. Li, H. Tang, H. Zhang, M. Wu, and Y. Ma (2016). The Stabilization of NiCo2O4 Nanobelts Used for Catalyzing Triiodides in Dye-sensitized Solar Cells by the Presence of RGO Sheets. Solar Energy Materials and Solar Cells, 149; 9–14
Faraji, S. and F. N. Ani (2015). The Development Supercapacitor from Activated Carbon by Electroless Plating—a Review. Renewable and Sustainable Energy Reviews, 42; 823–834
Han, D., P. Xu, X. Jing, J. Wang, P. Yang, Q. Shen, J. Liu, D. Song, Z. Gao, and M. Zhang (2013). Trisodium Citrate Assisted Synthesis of Hierarchical NiO Nanospheres with Improved Supercapacitor Performance. Journal of Power Sources, 235; 45–53
Jiang, J., Y. Zhang, P. Nie, G. Xu, M. Shi, J. Wang, Y. Wu, R. Fu, H. Dou, and X. Zhang (2018). Progress of Nanostructured Electrode Materials for Supercapacitors. Advanced Sustainable Systems, 2(1); 1700110
Jiang, M., L. Zhu, Q. Zhao, G. Chen, Z. Wang, J. Zhang, L. Zhang, J. Lei, and T. Duan (2022). Novel Synthesis of NaY-NH4F-Bi2S3 Composite for Enhancing Iodine Capture. Chemical Engineering Journal, 443; 136477
Karimi, F., S. Korkmaz, C. Karaman, O. Karaman, and İ. A. Kariper (2022). Engineering of GO/MWCNT/RuO2 Ternary Aerogel for High-performance Supercapacitor. Fuel, 329; 125398
Karthikeyan, S., B. Narenthiran, A. Sivanantham, L. D. Bhatlu, and T. Maridurai (2021). Supercapacitor: Evolution and Review. Materials Today, 46; 3984–3988
Km, D. K., J. G. Hong, J. Kweon, G. Saeed, K. H. Kim, D. Lee, and M. C. Kang (2022). Spinel NiCo2O4 Nanowires Synthesized on Ni Foam as Innovative Binder-free Supercapacitor Electrodes. Materials Chemistry and Physics, 291; 126718
Lamba, P., P. Singh, P. Singh, P. Singh, A. Kumar, M. Gupta, and Y. Kumar (2022). Recent Advancements in Supercapacitors Based on Different Electrode Materials: Classifications, Synthesis Methods and Comparative Performance. Journal of Energy Storage, 48; 103871
Lee, D., K. S. Kim, J. M. Yun, S. Y. Yoon, S. Mathur, H. C. Shin, and K. H. Kim (2019). Synergistic Effects of Dual Nano-type electrode of NiCo-nanowire/NiMn-nanosheet for High-energy Supercapacitors. Journal of Alloys and Compounds, 789; 119–128
Liu, R., A. Zhou, X. Zhang, J. Mu, H. Che, Y. Wang, T. T. Wang, Z. Zhang, and Z. Kou (2021). Fundamentals, Advances and Challenges of Transition Metal Compounds-based Supercapacitors. Chemical Engineering Journal, 412; 128611
Manalu, A., K. Tarigan, S. Humaidi, M. Ginting, and I. P. Manalu (2022). Effect of Surface Area on Electrical Properties of NiCo2O4-reduced Graphene Oxide Nanocomposites for Supercapacitor Electrodes Applications. Materials Science for Energy Technologies, 5; 444–451
Mehta, S., S. Jha, and H. Liang (2020). Lignocellulose Materials for Supercapacitor and Battery Electrodes: A Review. Renewable and Sustainable Energy Reviews, 134; 110345
Najib, S. and E. Erdem (2019). Current Progress Achieved in Novel Materials for Supercapacitor Electrodes: Mini Review. Nanoscale Advances, 1(8); 2817–2827
Nakhodchari, M. M., M. Seifi, and M. T. T. Moghadam (2023). Ternary MnCo2O4/MWCNT/rGO Nanocomposites as High-performance Supercapacitor Electrode Materials. Journal of Physics and Chemistry of Solids, 174; 111170
Offor, P., S. Ude, G. Whyte, F. Otung, I. Madiba, A. Bashir, N. Thovhogi, B. Okorie, and F. I. Ezema (2021). Effect of Concentration of Trisodium Citrate Complexing Agent on Spray-synthesized ZnS Thin Films. Materials Today: Proceedings, 36; 133–140
Paliwal, M. K. and S. K. Meher (2020). Co3O4/NiCo2O4 Perforated Nanosheets for High Energy Density All Solid State Asymmetric Supercapacitors with Extended Cyclic Stability. ACS Applied Nano Materials, 3(5); 4241–4252
Ren, H. and C. Huang (2022). Progress in Electrode Modification of Fibrous Supercapacitors. Journal of Energy Storage, 56; 106032
Saikia, B. K., S. M. Benoy, M. Bora, J. Tamuly, M. Pandey, and D. Bhattacharya (2020). A Brief Review on Supercapacitor Energy Storage Devices and Utilization of Natural Carbon Resources as Their Electrode Materials. Fuel, 282; 118796
Salarizadeh, P., M. B. Askari, M. Seifi, S. M. Rozati, and S. S. Eisazadeh (2020). Pristine NiCo2O4 Nanorods Loaded rGO Electrode as a Remarkable Electrode Material for Asymmetric Supercapacitors. Materials Science in Semiconductor Processing, 114; 105078
Shi, W., J. Zhu, D. H. Sim, Y. Y. Tay, Z. Lu, X. Zhang, Y. Sharma, M. Srinivasan, H. Zhang, and H. H. Hng (2011). Achieving High Specific Charge Capacitances in Fe 3 O 4/reduced Graphene Oxide Nanocomposites. Journal of Materials Chemistry, 21(10); 3422–3427
Simon, P. and Y. Gogotsi (2020). Perspectives for Electrochemical Capacitors and Related Devices. Nature Materials, 19(11); 1151–1163
Singh, A., S. K. Ojha, and A. K. Ojha (2020). Facile Synthesis of Porous Nanostructures of NiCo2O4 Grown on rGO Sheet for High Performance Supercapacitors. Synthetic Metals, 259; 116215
Wang, J., S. P. Feng, Y. Yang, N. Y. Hau, M. Munro, E. Ferreira Yang, and G. Chen (2015). “Thermal Charging” Phenomenon in Electrical Double Layer Capacitors. Nano Letters, 15(9); 5784–5790 Winter, M. and R. J. Brodd (2004). What are Batteries, Fuel Cells, and Supercapacitors? Chemical Reviews, 104(10); 4245–4270
Xing, S., Q. Wang, Z. Ma, Y. Wu, and Y. Gao (2012). Controlled Synthesis of Mesoporous ???? -Ni (OH) 2 and NiO Nanospheres with Enhanced Electrochemical Performance. Materials Research Bulletin, 47(9); 2120–2125
Zheng, H., X. Du, Q. Liu, K. Ou, Y. Cao, X. Fang, Q. Fu, and Y. Sun (2023). Self Healing and Wide Temperature Tolerant Flexible Supercapacitor Based on Ternary-network Organo-hydrogel Electrolyte. International Journal of Hydrogen Energy, 3(5); 34–39
Authors
Manalu, A., Manalu, I. P. ., Panjaitan, M. B. ., Simanullang, A. F. ., & Sitorus, P. . (2023). Characterization of Synthesized NiCo2O4 with Trisodium Citrate for Supercapacitor Material: A Preliminary Study. Science and Technology Indonesia, 8(2), 245–251. https://doi.org/10.26554/sti.2023.8.2.245-251
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