Synthesis and Characterization of Perovskite Manganate Based on La0.7Ca0.3MnO3 with Ni and Ti doping as Microwave Absorber Material
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Keywords:
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La0.7Ca0.3Mn1-xNix/2Tix/2O3 , Sol-Gel Method , Microwave Absorber
Abstract
Research has been carried out on the effect of Ni and Ti doping on the microwave absorption properties of the perovskite manganate material La0.7Ca0.3Mn1-xNix/2Tix/2O3 (LCMNTO) with variations x = 0; 0.03; 0.05; and 0.1, which were synthesized by the sol-gel method. The effect of Ni and Ti doping on the structure, grain size, magnetic properties, and microwave absorption properties were investigated in detail by various analytical methods. XRD (x-ray diffraction) characterization showed that the material La0.7Ca0.3Mn1-xNix/2Tix/2O3 has a single phase with an orthorhombic crystal system. The SEM (scanning electron microscope) results showed a tendency to decrease in grain size when the composition of Ni and Ti dopants began to increase. VSM (vibrating sample magnetometer) characterization shows that La0.7Ca0.3Mn1-xNix/2Tix/2O3 is a soft magnet with magnetic properties that decrease with increasing Ni and Ti dopant composition. The characterization of VNA (vector network analyzer) in the 8-12 GHz shows that the highest ability to absorb microwaves is 98% at 8.24 GHz, and there is an addition of absorption areas point and widening of the absorption bandwidth. Thus, the material La0.7Ca0.3Mn1-xNix/2Tix/2O3 has the potential to become a microwave absorber material.
References
Adi, W. A. and A. Manaf Ridwan (2017). Absorption Characteristics of the Electromagnetic Wave and Magnetic Properties of the La0.8Ba0.2FexMn1/2(1-X) Ti1/2(1-X) O3 (x= 0.1-0.8) Perovskite System. International Journal of Technology, 5(October); 887–897
Akinay, Y., U. Gunes, B. Çolak, and T. Cetin (2023). Recent Progress of Electromagnetic Wave Absorbers: A Systematic Review and Bibliometric Approach. ChemPhysMater, 2(3); 197–206
Akram, M., M. Umair, M. A. Yaqub, S. M. Ramay, S. Naseem, and S. Atiq (2023). Nanostructured Fe-Substituted LaMnO3 Perovskites as a High-Performance Electrode for Supercapacitors. ECS Journal of Solid State Science and Technology, 12(9); 093005
Alabada, R., M. M. Kadhim, Z. sabri Abbas, A. M. Rheima, U. S. Altimari, A. H. Dawood, Z. T. Abed, R. S. Radhi, A. S. Jaber, and S. K. Hachim (2023). Investigation of Effective Parameters in the Production of Alumina Gel through the Sol-Gel Method. Case Studies in Chemical and Environmental Engineering, 8(December); 100405
Ardani, A., S. A. Saptari, and A. Tjahjono (2021). Analysis the Increased of Nickel Substitution on Crystal Structure and Magnetic Properties of Lanthanum Barium Manganate Material. In AIP Conference Proceedings, volume 2382. AIP Publishing
Bakonyi, I. (2021). Accounting for the Resistivity Contribution of Grain Boundaries in Metals: Critical Analysis of Reported Experimental and Theoretical Data for Ni and Cu. The European Physical Journal Plus, 136(4); 410
Bishara, H., S. Lee, T. Brink, M. Ghidelli, and G. Dehm (2021). Understanding Grain Boundary Electrical Resistivity in Cu: The Effect of Boundary Structure. ACS Nano, 15(10); 16607–16615
Bouzidi, S., M. A. Gdaiem, J. Dhahri, and E. Hlil (2019). Large Magnetocaloric Entropy Change at Room Temperature in Soft Ferromagnetic Manganites. RSC Advances, 9(1); 65–76
Cheng, H., H. Chen, C. Jin, and H. Bai (2023). Modulating the Antiferromagnetic Metallic and Insulating States by Lattice Distortion for Lightly-Doped La0.92Sr0.08MnO3 Films. Journal of Magnetism and Magnetic Materials, 565(January); 170300
Cheng, Z., H. Zhen, A. Li, X. Wang, and H. Kimura (2005). CMR La0.7Ca0.3MnO3 and La0.7Sr0.3MnO3 Thin Films Fabricated by Sol–Gel Method. Journal of Crystal Growth, 275(1-2); e2415–e2419
Çoban Özkan, D., A. Türk, and E. Celik (2021). Synthesis and Characterizations of LaMnO3 Perovskite Powders Using Sol–Gel Method. Journal of Materials Science: Materials in Electronics, 32(11); 15544–15562
Dimri, M. C., H. Khanduri, and R. Stern (2021). Effects of Aliovalent Dopants in LaMnO3: Magnetic, Structural and Transport Properties. Journal of Magnetism and Magnetic Materials, 536(October); 168111
Elmahaishi, M. F., I. Ismail, and F. D. Muhammad (2022). A Review on Electromagnetic Microwave Absorption Properties: Their Materials and Performance. Journal of Materials Research and Technology, 20(September-October); 2188–2220
González García, I., A. Bolarín Miró, O. Rosales González, J. Aguirre Espinosa, C. CortésEsco bedo, and F. Sánchez De Jesús (2023). Effect of Cobalt on the Magnetic Properties and Temperature Coefficient of Resistance for Lanthanum-Strontium Manganite. Journal of Materials Science: Materials in Electronics, 34(29); 1979
He, S., Z. Wang, W. Qiu, H. Zhao, and Y. Lei (2024). Effect of Partial Cation Replacement on Anode Performance of Sodium-Ion Batteries. Batteries, 10(2); 44
Hua, S., P. Zhang, H. Yang, S. Zhang, and H. Ge (2013). The Magnetic and Magnetocaloric Properties of the Perovskite La0.7Ca0.3Mn1-xNixO3. Journal of Magnetics, 18(1); 34–38
Karoblis, D., K. Mazeika, D. Baltrunas, A. Lukowiak, W. Strek, A. Zarkov, and A. Kareiva (2020). Novel Synthetic Approach to the Preparation of Single-Phase BiXLa1-XMno3+δ Solid Solutions. Journal of Sol-Gel Science and Technology, 93(August); 650–656
Keshri, S., S. Rajput, S. Biswas, L. Joshi, W. Suski, and P. WiŚniewski (2021). Structural, Magnetic and Transport Properties of Ca and Sr Doped Lanthanum Manganites. Journal of Metals, Materials and Minerals, 31(4); 62–68
Khodayari, K. and A. Gholizadeh (2024). Exchange-Spring Behavior in Ni0·3Cu0·2Zn0·5Fe2O4/PbFe12O19 Nanocomposite. Physica Scripta, 99(3); 035932
Kurniawan, B., N. Sahara, A. Imadudin, I. Rahman, D. Razaq, and D. Munazat (2019). Structure, Microstructure, Electrical Transport Mechanism and Magnetoresistance in La0.8Ag0.2MnO3. In Journal of Physics: Conference Series, volume 1402. IOP Publishing, page 066011
Liu, J. W., J. J. Wang, and H. T. Gao (2018). Infrared Emissivities and Microwave Absorption Properties of Perovskite La1-xCaxMnO3 (0 ≤ x ≤ 0.5). In Materials Science Forum, volume 914. Trans Tech Publ, pages 96–101
Mehner, T., M. Uland, and T. Lampke (2020). Analytical Model to Calculate the Grain Size of Bulk Material Based on Its Electrical Resistance. Metals, 11(1); 21
Mu, Z., G. Wei, H. Zhang, L. Gao, Y. Zhao, S. Tang, and G. Ji (2022). The Dielectric Behavior and Efficient Microwave Absorption of Doped Nanoscale LaMnO3 at Elevated Temperature. Nano Research, 15(8); 7731–7741
Navas, D., S. Fuentes, A. Castro-Alvarez, and E. Chavez-Angel (2021). Review on Sol-Gel Synthesis of Perovskite and Oxide Nanomaterials. Gels, 7(4); 275
Reddy, A. V., K. Sekhar, N. Dabra, A. Nautiyal, J. S. Hundal, N. Pathak, and R. Nath (2011). Ferroelectric and Magnetic Properties of Hot-Pressed BiFeO3-PVDF Composite Films. International Scholarly Research Notices, 2011(July); 1–5
Rizky, F., S. A. Saptari, A. Tjahjono, and D. S. Khaerudini (2022). Perovskite Manganit Analysis Based onLa0.7Ca0.3Mn1-xTixO3 (x= 0, 0.1, 0.2, and 0.3) as Potential Microwave Absorber Material with Sol-Gel Method. Journal of Physics: Theories and Applications, 6(1); 17–24
Saptari, S. A., N. H. Lathifah, A. Tjahjono, and D. Shidqi (2022). Analysis of Crystal Structure and Reflection Loss of Material Based on La0.7Sr0.3Mn1-x (ni, Ti) x/2O3 (x= 0.1, 0.3, and 0.5) Applications for Microwave Absorbers. Journal of Physics: Theories and Applications, 6(2); 106-115
Saradva, A. R. (2023). Radiation impact from Cell Phones and Towers on Human Health and Environment-A Review. International Journal of Scientific Research in Science and Technology, 10(1); 537–541
Suresh, S., P. Vindhya, S. Devika, and V. Kavitha (2023). Structural, Optical and Dielectric Properties of Nanostructured La1-xSrxMnO3 Perovskites. Materials Today Communications, 36(August); 106657
Taşarkuyu, E., A. Coşkun, A. Irmak, S. Aktürk, G. Ünlü, Y. Samancıoğlu, A. Yücel, C. Sarıkürkçü, S. Aksoy, and M. Acet (2011). Effect of High Temperature Sintering on the Structural and the Magnetic Properties of La1·4Ca1·6Mn2O7. Journal of Alloys and Compounds, 509(9); 3717–3722
Ulyanov, A. N., Y. M. Kang, S. I. Yoo, D. S. Yang, H. M. Park, K. W. Lee, and S. C. Yu (2006). Local Structure and Electron Configuration Effects on Curie Temperature in La0.7Ca0.3Mn1-xTixO3 Lanthanum Manganites. Journal of Magnetism and Magnetic Materials, 304(1); e331–e333
Xu, H., H. Zhang, Y. Ma, M. Jiang, Y. Zhang, Y. Wu, H. Zhang, R. Xia, Q. Niu, and X. Li (2019). Morphology Control of Organic Halide Perovskites by Adding BiFeO3 Nanostructures for Efficient Solar Cell. Scientific Reports, 9(1); 15441
Ye, X., S. Dong, X. Jin, J. Wei, L. Wang, and Y. Zhang (2022). Enhancement in the Electrochemical Performance of Strontium (sr)-Doped LaMnO3 As Supercapacitor Materials. Coatings, 12(11); 1739
Zhang, F., Y. Chen, Y. Ren, Q. Zheng, L. Wang, and W. Jiang (2022). Anionic MOF Derived Bimetallic NixCoy@ Nano-Porous Carbon Composites toward Strong and Efficient Electromagnetic Wave Absorption. Journal of Materiomics, 8(4); 852–862
Zhang, H. G., Y. J. Zhang, W. H. Wang, and G. H. Wu (2011). Origin of the Constricted Hysteresis Loop in Cobalt Ferrites Revisited. Journal of Magnetism and Magnetic Materials, 323(15); 1980-1984
Zhang, S. and Q. Cao (2012). Electromagnetic and Microwave Absorption Performance of Some Transition Metal Doped La0.7Sr0.3Mn1-xTMxO3±???? (TM= Fe, Co or Ni). Materials Science and Engineering: B, 177(9); 678–684
Zheng, J., H. Zhao, X. Guo, X. Jin, L. Wang, S. Dong, and J. Chen (2023). Enhanced Electrochemical Performance of LaMnO3 Nanoparticles by Ca/Sr Doping. Coatings, 14(1); 20
Akinay, Y., U. Gunes, B. Çolak, and T. Cetin (2023). Recent Progress of Electromagnetic Wave Absorbers: A Systematic Review and Bibliometric Approach. ChemPhysMater, 2(3); 197–206
Akram, M., M. Umair, M. A. Yaqub, S. M. Ramay, S. Naseem, and S. Atiq (2023). Nanostructured Fe-Substituted LaMnO3 Perovskites as a High-Performance Electrode for Supercapacitors. ECS Journal of Solid State Science and Technology, 12(9); 093005
Alabada, R., M. M. Kadhim, Z. sabri Abbas, A. M. Rheima, U. S. Altimari, A. H. Dawood, Z. T. Abed, R. S. Radhi, A. S. Jaber, and S. K. Hachim (2023). Investigation of Effective Parameters in the Production of Alumina Gel through the Sol-Gel Method. Case Studies in Chemical and Environmental Engineering, 8(December); 100405
Ardani, A., S. A. Saptari, and A. Tjahjono (2021). Analysis the Increased of Nickel Substitution on Crystal Structure and Magnetic Properties of Lanthanum Barium Manganate Material. In AIP Conference Proceedings, volume 2382. AIP Publishing
Bakonyi, I. (2021). Accounting for the Resistivity Contribution of Grain Boundaries in Metals: Critical Analysis of Reported Experimental and Theoretical Data for Ni and Cu. The European Physical Journal Plus, 136(4); 410
Bishara, H., S. Lee, T. Brink, M. Ghidelli, and G. Dehm (2021). Understanding Grain Boundary Electrical Resistivity in Cu: The Effect of Boundary Structure. ACS Nano, 15(10); 16607–16615
Bouzidi, S., M. A. Gdaiem, J. Dhahri, and E. Hlil (2019). Large Magnetocaloric Entropy Change at Room Temperature in Soft Ferromagnetic Manganites. RSC Advances, 9(1); 65–76
Cheng, H., H. Chen, C. Jin, and H. Bai (2023). Modulating the Antiferromagnetic Metallic and Insulating States by Lattice Distortion for Lightly-Doped La0.92Sr0.08MnO3 Films. Journal of Magnetism and Magnetic Materials, 565(January); 170300
Cheng, Z., H. Zhen, A. Li, X. Wang, and H. Kimura (2005). CMR La0.7Ca0.3MnO3 and La0.7Sr0.3MnO3 Thin Films Fabricated by Sol–Gel Method. Journal of Crystal Growth, 275(1-2); e2415–e2419
Çoban Özkan, D., A. Türk, and E. Celik (2021). Synthesis and Characterizations of LaMnO3 Perovskite Powders Using Sol–Gel Method. Journal of Materials Science: Materials in Electronics, 32(11); 15544–15562
Dimri, M. C., H. Khanduri, and R. Stern (2021). Effects of Aliovalent Dopants in LaMnO3: Magnetic, Structural and Transport Properties. Journal of Magnetism and Magnetic Materials, 536(October); 168111
Elmahaishi, M. F., I. Ismail, and F. D. Muhammad (2022). A Review on Electromagnetic Microwave Absorption Properties: Their Materials and Performance. Journal of Materials Research and Technology, 20(September-October); 2188–2220
González García, I., A. Bolarín Miró, O. Rosales González, J. Aguirre Espinosa, C. CortésEsco bedo, and F. Sánchez De Jesús (2023). Effect of Cobalt on the Magnetic Properties and Temperature Coefficient of Resistance for Lanthanum-Strontium Manganite. Journal of Materials Science: Materials in Electronics, 34(29); 1979
He, S., Z. Wang, W. Qiu, H. Zhao, and Y. Lei (2024). Effect of Partial Cation Replacement on Anode Performance of Sodium-Ion Batteries. Batteries, 10(2); 44
Hua, S., P. Zhang, H. Yang, S. Zhang, and H. Ge (2013). The Magnetic and Magnetocaloric Properties of the Perovskite La0.7Ca0.3Mn1-xNixO3. Journal of Magnetics, 18(1); 34–38
Karoblis, D., K. Mazeika, D. Baltrunas, A. Lukowiak, W. Strek, A. Zarkov, and A. Kareiva (2020). Novel Synthetic Approach to the Preparation of Single-Phase BiXLa1-XMno3+δ Solid Solutions. Journal of Sol-Gel Science and Technology, 93(August); 650–656
Keshri, S., S. Rajput, S. Biswas, L. Joshi, W. Suski, and P. WiŚniewski (2021). Structural, Magnetic and Transport Properties of Ca and Sr Doped Lanthanum Manganites. Journal of Metals, Materials and Minerals, 31(4); 62–68
Khodayari, K. and A. Gholizadeh (2024). Exchange-Spring Behavior in Ni0·3Cu0·2Zn0·5Fe2O4/PbFe12O19 Nanocomposite. Physica Scripta, 99(3); 035932
Kurniawan, B., N. Sahara, A. Imadudin, I. Rahman, D. Razaq, and D. Munazat (2019). Structure, Microstructure, Electrical Transport Mechanism and Magnetoresistance in La0.8Ag0.2MnO3. In Journal of Physics: Conference Series, volume 1402. IOP Publishing, page 066011
Liu, J. W., J. J. Wang, and H. T. Gao (2018). Infrared Emissivities and Microwave Absorption Properties of Perovskite La1-xCaxMnO3 (0 ≤ x ≤ 0.5). In Materials Science Forum, volume 914. Trans Tech Publ, pages 96–101
Mehner, T., M. Uland, and T. Lampke (2020). Analytical Model to Calculate the Grain Size of Bulk Material Based on Its Electrical Resistance. Metals, 11(1); 21
Mu, Z., G. Wei, H. Zhang, L. Gao, Y. Zhao, S. Tang, and G. Ji (2022). The Dielectric Behavior and Efficient Microwave Absorption of Doped Nanoscale LaMnO3 at Elevated Temperature. Nano Research, 15(8); 7731–7741
Navas, D., S. Fuentes, A. Castro-Alvarez, and E. Chavez-Angel (2021). Review on Sol-Gel Synthesis of Perovskite and Oxide Nanomaterials. Gels, 7(4); 275
Reddy, A. V., K. Sekhar, N. Dabra, A. Nautiyal, J. S. Hundal, N. Pathak, and R. Nath (2011). Ferroelectric and Magnetic Properties of Hot-Pressed BiFeO3-PVDF Composite Films. International Scholarly Research Notices, 2011(July); 1–5
Rizky, F., S. A. Saptari, A. Tjahjono, and D. S. Khaerudini (2022). Perovskite Manganit Analysis Based onLa0.7Ca0.3Mn1-xTixO3 (x= 0, 0.1, 0.2, and 0.3) as Potential Microwave Absorber Material with Sol-Gel Method. Journal of Physics: Theories and Applications, 6(1); 17–24
Saptari, S. A., N. H. Lathifah, A. Tjahjono, and D. Shidqi (2022). Analysis of Crystal Structure and Reflection Loss of Material Based on La0.7Sr0.3Mn1-x (ni, Ti) x/2O3 (x= 0.1, 0.3, and 0.5) Applications for Microwave Absorbers. Journal of Physics: Theories and Applications, 6(2); 106-115
Saradva, A. R. (2023). Radiation impact from Cell Phones and Towers on Human Health and Environment-A Review. International Journal of Scientific Research in Science and Technology, 10(1); 537–541
Suresh, S., P. Vindhya, S. Devika, and V. Kavitha (2023). Structural, Optical and Dielectric Properties of Nanostructured La1-xSrxMnO3 Perovskites. Materials Today Communications, 36(August); 106657
Taşarkuyu, E., A. Coşkun, A. Irmak, S. Aktürk, G. Ünlü, Y. Samancıoğlu, A. Yücel, C. Sarıkürkçü, S. Aksoy, and M. Acet (2011). Effect of High Temperature Sintering on the Structural and the Magnetic Properties of La1·4Ca1·6Mn2O7. Journal of Alloys and Compounds, 509(9); 3717–3722
Ulyanov, A. N., Y. M. Kang, S. I. Yoo, D. S. Yang, H. M. Park, K. W. Lee, and S. C. Yu (2006). Local Structure and Electron Configuration Effects on Curie Temperature in La0.7Ca0.3Mn1-xTixO3 Lanthanum Manganites. Journal of Magnetism and Magnetic Materials, 304(1); e331–e333
Xu, H., H. Zhang, Y. Ma, M. Jiang, Y. Zhang, Y. Wu, H. Zhang, R. Xia, Q. Niu, and X. Li (2019). Morphology Control of Organic Halide Perovskites by Adding BiFeO3 Nanostructures for Efficient Solar Cell. Scientific Reports, 9(1); 15441
Ye, X., S. Dong, X. Jin, J. Wei, L. Wang, and Y. Zhang (2022). Enhancement in the Electrochemical Performance of Strontium (sr)-Doped LaMnO3 As Supercapacitor Materials. Coatings, 12(11); 1739
Zhang, F., Y. Chen, Y. Ren, Q. Zheng, L. Wang, and W. Jiang (2022). Anionic MOF Derived Bimetallic NixCoy@ Nano-Porous Carbon Composites toward Strong and Efficient Electromagnetic Wave Absorption. Journal of Materiomics, 8(4); 852–862
Zhang, H. G., Y. J. Zhang, W. H. Wang, and G. H. Wu (2011). Origin of the Constricted Hysteresis Loop in Cobalt Ferrites Revisited. Journal of Magnetism and Magnetic Materials, 323(15); 1980-1984
Zhang, S. and Q. Cao (2012). Electromagnetic and Microwave Absorption Performance of Some Transition Metal Doped La0.7Sr0.3Mn1-xTMxO3±???? (TM= Fe, Co or Ni). Materials Science and Engineering: B, 177(9); 678–684
Zheng, J., H. Zhao, X. Guo, X. Jin, L. Wang, S. Dong, and J. Chen (2023). Enhanced Electrochemical Performance of LaMnO3 Nanoparticles by Ca/Sr Doping. Coatings, 14(1); 20
Authors
Saptari, S. A., Mar’ah, M. ., Taryana, Y. ., & Sudrajat, N. . (2024). Synthesis and Characterization of Perovskite Manganate Based on La0.7Ca0.3MnO3 with Ni and Ti doping as Microwave Absorber Material. Science and Technology Indonesia, 9(3), 577–585. https://doi.org/10.26554/sti.2024.9.3.577-585
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